AIR-WATER INTERFACIAL AREA AND CAPILLARY PRESSURE: POROUS-MEDIUM EXTURE EFFECTS AND AN EMPIRICAL FUNCTION
1School of Environment, Beijing Normal University, Key Laboratory of Water and Sediment Sciences of Ministry of Education, Beijing, 100875, China.
Summary
The air-water interfacial area increases with capillary pressure in natural porous media, with maximums dependent on residual water saturation. Sorting affects the rate of change, and a coupled equation reasonably simulates the observed data.
Area of Science:
- Porous media physics
- Soil science
- Environmental engineering
Background:
- Understanding air-water interfacial area is crucial for modeling unsaturated flow in porous media.
- Capillary pressure governs fluid distribution and interfacial phenomena in soils and rocks.
- Previous studies have explored these relationships, but higher water-content conditions require further investigation.
Purpose of the Study:
- To investigate the relationship between air-water interfacial area and capillary pressure in natural porous media at higher water contents.
- To determine how porous medium properties, such as sorting, influence this relationship.
- To develop a quantitative model for predicting air-water interfacial area based on capillary pressure.
Main Methods:
- Experimental investigation of four natural porous media under varying water content conditions.
- Measurement of air-water interfacial area and capillary pressure.
- Analysis of the influence of pore-size distribution and sorting on the observed relationships.
- Coupling empirical and established equations (van Genuchten) to model the data.
Main Results:
- Air-water interfacial area increases with increasing capillary pressure, correlating with decreasing water saturation.
- Maximum air-water interfacial areas are limited by residual water saturation, which varies with conditions.
- Better-sorted media show a higher rate of change in interfacial area with capillary pressure compared to poorly-sorted media.
- The coupled empirical and van Genuchten model accurately simulated the experimental data.
Conclusions:
- The relationship between air-water interfacial area and capillary pressure is well-defined in natural porous media.
- Porous medium characteristics, particularly sorting, significantly impact the dynamics of interfacial area.
- A combined modeling approach provides a reliable method for predicting interfacial area under varying capillary pressures.
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