Magnetic properties and chiral states of a trimetallic uranium complex
S Carretta1, G Amoretti, P Santini
1Dipartimento di Fisica e Scienze della Terra, Università di Parma, and Unità CNISM di Parma, Viale G P Usberti 7/A, I-43124 Parma, Italy.
Abstract:
The magnetic properties of the triangular molecular nanomagnet [UO2L]3 (L = 2-(4-tolyl)-1,3-bis(quinolyl)malondiiminate) have been investigated through electron paramagnetic resonance spectroscopy, high-field magnetization and susceptibility measurements. The experimental findings are well reproduced by a microscopic model including exchange interactions and local crystal fields. These results show that [UO2L]3 is characterized by a non-magnetic ground doublet corresponding to two oppositely twisted chiral arrangements of the uranium moments. The non-axial character of single-ion crystal fields leads to quantum tunneling of the noncollinear magnetization in the presence of a magnetic field applied perpendicularly to the triangle plane.
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