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Methoxy-directed aryl-to-aryl 1,3-rhodium migration

Jing Zhang1, Jun-Feng Liu, Angel Ugrinov

  • 1Department of Chemistry and Biochemistry, North Dakota State University , Fargo, North Dakota 58102, United States.

Journal of the American Chemical Society
|November 1, 2013
PubMed
Summary

This study details a unique 1,3-rhodium migration in a Rh(I) complex, enabling meta-selective C-C bond formation via decarboxylative conjugate addition and C-H activation.

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