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Gold-catalyzed rearrangements and beyond

Carla Obradors1, Antonio M Echavarren

  • 1Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16, 43007 Tarragona, Spain.

Accounts of Chemical Research
|November 2, 2013
PubMed
Summary

Gold(I) catalysis enables efficient cycloisomerization of enynes, forming complex molecular architectures. This study reveals gold(I)-stabilized cationic intermediates, crucial for various carbon-carbon bond-forming reactions and natural product synthesis.

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