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Photophysical properties ofβ-homo-tyrosine derivatives
L Lankiewicz1, J Lanoszka, S Ołdziej
1Faculty of Chemistry, University of Gdańsk, Sobieskiego 18, PL-80-952, Gdańsk, Poland.
Abstract:
The observed monoexponential fluorescence decay of N-acetyl-β-homo-tyrosine methylamide (Ac-βHty-NHMe) (I) and N-acetyl-(O-methyl)-β-homo-tyrosine methylamide (Ac-βHty(OMe)-NHMe) (II) is supporting the rotamer population theory, according to which rotamers are responsible for heterogeneity of the fluorescence decay of N-acetyl-tyrosine amide or tyrosine incorporated within a peptide chain, in general.
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