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Summary

We developed a simple mechanical model to explain the pulsating behavior of sessile drops. This model captures the complex dynamics of liquid/liquid systems, aiding in understanding drop evaporation and dissolution phenomena.

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Area of Science:

  • Fluid dynamics
  • Non-equilibrium thermodynamics
  • Physical chemistry

Background:

  • Self-pulsating sessile drops exhibit complex dynamics not fully understood.
  • Simple models are needed to elucidate the mechanisms behind these far-from-equilibrium liquid/liquid systems.

Purpose of the Study:

  • To present a simple mass-spring mechanical model for drop pulsations.
  • To explain the periodic rim breakup observed in dissolving dichloromethane drops.

Main Methods:

  • Developed a mass-spring mechanical model.
  • Introduced an effective time-dependent spreading coefficient.
  • Compared model predictions with experimental observations.

Main Results:

  • The model successfully replicates the regular drop pulsations.
  • Rapid spreading phases of pulsations are explained.
  • Periodic rim breakup is accounted for by the model.

Conclusions:

  • The mass-spring model provides a simplified yet effective framework for understanding sessile drop pulsations.
  • The time-dependent spreading coefficient effectively integrates various physical forces influencing drop dynamics.
  • Further research can build upon this model to explore more complex liquid/liquid systems.