Related Experiment Video
Updated: May 6, 2026

Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
Published on: May 29, 2018
Stochastic kinetics of photoinduced phase transitions in spin-crossover solids
Iurii Gudyma1, Artur Maksymov, Mihai Dimian
1Department of General Physics, Chernivtsi National University, 58012 Chernivtsi, Ukraine.
Abstract:
We study the stochastic macroscopic kinetics of photoinduced phase transitions in spin-crossover compounds assisted by white and colored Ornstein-Uhlenbeck noise. By using a phenomenological master equation obtained in the mean-field approach, the phase diagram is constructed based on the associated Lyapunov function. The stochastic behavior is then analyzed in the Langevin framework and the corresponding Fokker-Planck equations. Both additive and multiplicative and white and colored types of noise are considered and the stationary probability densities are found along with the noise-assisted light induced hysteretic loops. By using the Kramers formalism, we also focus our attention on the escape time problem in these noise perturbed systems. A detailed study of the relative escape time dependence on various noise characteristics is performed and the main features are compared for different types of noise.
More Related Videos
Related Concept Videos
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Transition State Theory
Phase Transitions
Phase Transitions
Cooperative Allosteric Transitions
Cooperative Allosteric Transitions

