Intermolecular Foerster's energy transfer in labeled poly[N-(2-hydroxypropyl)methacrylamide]
D Vyprachticky1, V Pokorná, F Mikes
1Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovský Sq. 2, 162 06, Prague 6, Czech Republic.
Abstract:
By copolymerization of monomers containing donor (carbazole) and acceptor (dansyl) fluorophores withN-(2-hydroxypropyl)methacrylamide (HPMA), statistical copolymers with "low" and "high" contents of the fluorophores were prepared. The increase in nonradiative energy transfer between copolymers with a low content of fluorophores was probably due to intermolecular penetration of the polymer coils in concentrated solutions.
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