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Easily solution-processed, high-performance microribbon transistors based on a 2D condensed benzothiophene

Xiaoxia Liu1, Yingfeng Wang, Jianhua Gao

  • 1Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, P. R. China. gaojh@hznu.edu.cn.

Chemical Communications (Cambridge, England)
|November 21, 2013
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Summary

A novel 2D benzothiophene derivative, TBTDBT, was synthesized and its properties investigated. Organic field-effect transistors fabricated from TBTDBT microribbons demonstrated high mobility and on-off ratios.

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Area of Science:

  • Materials Science
  • Organic Electronics
  • Solid State Chemistry

Background:

  • Organic semiconductors are crucial for developing flexible and low-cost electronic devices.
  • Benzothiophene derivatives offer tunable electronic properties for advanced applications.

Purpose of the Study:

  • To synthesize a novel 2D condensed benzothiophene derivative, TBTDBT.
  • To investigate the thermal, optical, and electrochemical properties of TBTDBT.
  • To fabricate and characterize organic field-effect transistors (OFETs) using TBTDBT.

Main Methods:

  • Synthesis of the 2D benzothiophene derivative TBTDBT.
  • Crystal growth via solution drop-casting and physical vapor transport.
  • Fabrication of OFETs using TBTDBT microribbons.

Main Results:

  • TBTDBT microribbons were successfully grown using two distinct methods.
  • Field-effect transistors exhibited high charge carrier mobility up to 2.62 cm(2) V(-1) s(-1).
  • An excellent on-off ratio exceeding 10(5) was achieved, indicating efficient transistor switching.

Conclusions:

  • TBTDBT is a promising organic semiconductor material for high-performance OFETs.
  • The synthesized material shows potential for applications in organic electronics.
  • The study highlights the structure-property relationship in 2D benzothiophene derivatives.