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Micelles01:30

Micelles

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Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...
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Surface Active Agents01:27

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Surfactants, named for their behavior at interfaces, positively adsorb at the interfaces of two phases, reducing interfacial tension. Their versatility as emulsifiers, detergents, and foaming agents stems from this ability. Surfactants, often termed amphiphiles, share the property of amphipathy, with molecules having both hydrophilic and hydrophobic portions. The hydrophilic part is called the head, and the hydrophobic part, including an elongated alkyl substituent, forms the tail.Surfactants...
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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Dissolution kinetics, an essential aspect of oral drug delivery, is significantly influenced by the drug's particle size. According to the Noyes-Whitney dissolution model, the dissolution rate correlates directly with the drug's surface area. The larger the surface area, the higher the drug's solubility in water, leading to a faster drug dissolution rate. Reducing particle size increases the effective surface area, enhancing the dissolution process. Micronization and nanosizing are...
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Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
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The process of breathing, inhaling and exhaling, involves the coordinated movement of the chest wall, the lungs, and the muscles that move them. Two muscle groups with important roles in breathing are the diaphragm, located directly below the lungs, and the intercostal muscles, which lie between the ribs. When the diaphragm contracts, it moves downward, increasing the volume of the thoracic cavity and creating more room for the lungs to expand. When the intercostal muscles contract, the ribs...
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Related Experiment Video

Updated: May 5, 2026

Studying Surfactant Effects on Hydrate Crystallization at Oil-Water Interfaces Using a Low-Cost Integrated Modular Peltier Device
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Studying Surfactant Effects on Hydrate Crystallization at Oil-Water Interfaces Using a Low-Cost Integrated Modular Peltier Device

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Surfactant micelles containing solubilized oil decrease foam film thickness stability.

Jongju Lee1, Alex Nikolov, Darsh Wasan

  • 1Department of Chemical and Biological Engineering, Illinois Institute of Technology, Chicago, IL 60616, USA.

Journal of Colloid and Interface Science
|November 26, 2013
PubMed
Summary
This summary is machine-generated.

Solubilized oil within surfactant micelles significantly destabilizes three-phase foams. This study reveals that swollen micelles reduce the structural energy barrier, leading to decreased foam stability.

Keywords:
Aqueous foamsFoam stabilitySingle foam film stabilitySwollen micelles

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Area of Science:

  • Colloid and Surface Science
  • Foam Stability
  • Surfactant Micelles

Background:

  • Three-phase foams (oil-in-water) are crucial in industrial applications.
  • Surfactants are used above their critical micelle concentration (CMC).
  • Oil can exist as drops or be solubilized within micelles, impacting foam properties.

Purpose of the Study:

  • To investigate the effect of oil solubilized in surfactant micelles on foam stability.
  • To elucidate the mechanism by which swollen micelles influence foam structure and stability.
  • To understand the role of oil-in-surfactant systems in foam performance.

Main Methods:

  • Studied the stability of a single foam film containing swollen sodium dodecyl sulfate (SDS) micelles.
  • Employed reflected light microinterferometry to observe film thinning and stratification.
  • Measured film-meniscus contact angle versus film thickness to calculate structural energy isotherms.

Main Results:

  • Observed stepwise film thinning (stratification) in the presence of swollen micelles.
  • Found that swollen micelles decrease the structural energy stabilization barrier of foam films.
  • Demonstrated that oil drops (macroemulsions) did not significantly affect foam stability, unlike solubilized oil.

Conclusions:

  • Solubilized oil within surfactant micelles significantly reduces foam stability.
  • The presence of swollen micelles lowers the energy barrier, leading to less stable foams.
  • This research provides critical insights into the destabilizing role of solubilized oil in surfactant-based foams.