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Updated: May 5, 2026

Preparation of DMMTAV and DMDTAV Using DMAV for Environmental Applications: Synthesis, Purification, and Confirmation
Published on: March 9, 2018
Synthesis and characterization of NpCl4(DME)2 and PuCl4(DME)2 neutral transuranic An(IV) starting materials
Sean D Reilly1, Jessie L Brown, Brian L Scott
1Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. gaunt@lanl.gov.
Abstract:
The 1,2-dimethoxyethane (DME) solvento adducts of Np(iv) and Pu(iv) tetrachloride have been prepared and isolated in good and moderate yields, respectively, along with single-crystal structural determinations. These neutral molecules are expected to provide alternative synthetic pathways in the pursuit of non-aqueous and organometallic complexes.
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