Oxidative C(sp3)-H bond cleavage, C-C and C=C coupling at a boron center with O2 as the oxidant mediated by
S Pal1, P Y Zavalij, A N Vedernikov
1Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA. avederni@umd.edu.
Chemical Communications (Cambridge, England)
|November 30, 2013
Abstract:
Dimethyl- and diphenylplatinum(II) fragments Pt(II)R2 (R = Me, Ph) enable facile and efficient oxidative C(sp(3))-H bond cleavage and stepwise C-C and C=C coupling at the boron atom of a coordinated 1,5-cyclooctanediyldi(2-pyridyl)borato ligand with O2 as the sole oxidant.
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