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Updated: May 5, 2026

Generation of Zerovalent Metal Core Nanoparticles Using n-2-aminoethyl-3-aminosilanetriol
Published on: February 11, 2016
Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center
Alexander C Filippou1, Bernhard Baars, Oleg Chernov
1Institut für Anorganische Chemie, Universität Bonn, Gerhard-Domagk-Strasse 1, 53121 Bonn (Germany) http://www.filippou.chemie.uni-bonn.de. filippou@uni-bonn.de.
Abstract:
SiO in a complex: The first silanone that is stable at room temperature (3) is reported. The two-step synthesis involves carbonylation of the silylidyne complex 1 to give the chromiosilylene 2, followed by oxidation of 2 with N2 O. Silanone 3 features a polar, short SiO bond (1.526(3) Å) to a trigonal-planar-coordinated silicon center and reacts with water to give the dihydroxysilyl complex.
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