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An unusual example of hypervalent silicon: a five-coordinate silyl group bridging two palladium or nickel centers

Ainara Nova1, Hee-Won Suh, Timothy J Schmeier

  • 1Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Oslo, P.O. Box 1033, Blindern, 0315 Oslo (Norway); Institute of Chemical Research of Catalonia (ICIQ), Avgda Països Catalans, 16, 43007 Tarragona (Spain). ainara.nova@kjemi.uio.no.

Angewandte Chemie (International Ed. in English)
|December 17, 2013
PubMed

Keywords:
electronic structurefour-center two-electron bondshypervalent siliconnickelpalladium

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