Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

1.4K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
1.4K
Free-Radical Chain Reaction and Polymerization of Alkenes02:35

Free-Radical Chain Reaction and Polymerization of Alkenes

8.4K
The conversion of alkenes to macromolecules called polymers is a reaction of high commercial importance. The structure of the polymer is defined by a repeating unit, while the terminal groups are considered insignificant. The average degree of polymerization represents the number of repeating units in the polymer molecule and is denoted by the subscript n.
8.4K
Olefin Metathesis Polymerization: Overview01:13

Olefin Metathesis Polymerization: Overview

1.8K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
1.8K
Anionic Chain-Growth Polymerization: Overview01:20

Anionic Chain-Growth Polymerization: Overview

1.8K
The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
1.8K
Solvents01:12

Solvents

58.5K
A solvent is a substance, most often a liquid, that can dissolve other substances. Here, the substance being dissolved is called a solute. When a solvent and a solute combine, they form a solution - a homogenous mixture of both the solvent and the solute. Water is a universal biological solvent. Its polar structure allows it to dissolve many other polar compounds. The ability of water to dissolve is governed by a balance between water molecules binding to each other and binding to the solute.
A...
58.5K
Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

2.1K
The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
2.1K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Lessons From Deep Eutectic Solvents to Design High Entropy Electrolytes for Electrochemical Energy Storage.

ChemSusChem·2026
Same author

Excess Properties of Aqueous Dilutions of Ammonium- and Phosphonium-Based Deep Eutectic Solvents.

Journal of chemical and engineering data·2026
Same author

A regenerative rehabilitation strategy based on rGO scaffolds and treadmill training boosts neural, vascular and muscle repair features in chronic hemisected rats.

Biomaterials·2026
Same author

Beyond the Hype: Decoding Bis(fluorosulfonyl)imide Chemistry in Advanced Lithium-Sulfur Batteries.

Small methods·2026
Same author

Phytic Acid-Based Deep Eutectic Solvents for Metal Extraction from Lithium Cobalt Oxide and Nickel Manganese Cobalt and the Use of the Resulting Leachates as Electrolytes for 2.0 V Supercapacitors.

ChemSusChem·2025
Same author

Perinatal Protein Restriction Induces Anhedonic-Like Behavior: Disturbed Hippocampal Neurotrophic Signaling and Neuronal Structural Plasticity in Adult Offspring.

Hippocampus·2025

Related Experiment Video

Updated: May 4, 2026

Preparation of Binary and Ternary Deep Eutectic Systems
06:15

Preparation of Binary and Ternary Deep Eutectic Systems

Published on: October 31, 2019

13.0K

Deep eutectic solvents in polymerizations: a greener alternative to conventional syntheses.

Francisco del Monte1, Daniel Carriazo, María C Serrano

  • 1Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC), Campus de Cantoblanco, 28049 Madrid (Spain). delmonte@icmm.csic.es.

Chemsuschem
|December 31, 2013
PubMed
Summary

Deep eutectic solvents (DESs) offer a green alternative in materials science, acting as solvent-template-reactant systems. These DES-assisted syntheses reduce waste and energy, promoting eco-friendly material development.

Keywords:
eutectic solventsgreen chemistryionic liquidsmaterials sciencepolymerization

More Related Videos

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
09:16

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene

Published on: May 20, 2019

7.1K
Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
08:12

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

3.1K

Related Experiment Videos

Last Updated: May 4, 2026

Preparation of Binary and Ternary Deep Eutectic Systems
06:15

Preparation of Binary and Ternary Deep Eutectic Systems

Published on: October 31, 2019

13.0K
Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene
09:16

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in PolyS-Divinylbenzene

Published on: May 20, 2019

7.1K
Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
08:12

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

3.1K

Area of Science:

  • Materials Science
  • Green Chemistry
  • Polymer Chemistry

Background:

  • Conventional syntheses in materials science often involve harsh conditions and generate significant waste.
  • Deep eutectic solvents (DESs) are emerging as sustainable alternatives due to their unique properties.
  • DESs can function as integrated solvent, template, and reactant systems.

Purpose of the Study:

  • To provide a comprehensive overview of DES-assisted syntheses in materials science.
  • To compare DES-assisted methods with conventional syntheses, highlighting similarities and differences.
  • To rationalize the green chemistry principles exemplified by DES-assisted polymerizations.

Main Methods:

  • Review of three DES-assisted polymerization cases: one radical polymerization and two polycondensations.
  • Analysis of DES composition and its role in directing material structure and functionality.
  • Evaluation of DES-assisted syntheses against the 12 principles of green chemistry.

Main Results:

  • DESs incorporate precursors and functional components, enabling solventless polymerizations.
  • DES-assisted syntheses demonstrate reagent and solvent economy (Green Chemistry Principles 2 & 5).
  • Incorporated functionality minimizes post-synthesis modifications (Principle 8), while efficient precursors reduce energy input (Principle 6).

Conclusions:

  • DES-assisted syntheses offer a green and efficient route for polymer development.
  • The compositional versatility of DESs facilitates the design of biocompatible and eco-friendly materials (Principle 3).
  • DESs represent a promising platform for sustainable materials science and polymer synthesis.