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Updated: May 4, 2026

High Resolution Physical Characterization of Single Metallic Nanoparticles
Published on: June 28, 2019
An unusual metallic oxygen cluster consisting of a {AlMo12O40(MoO2)}
Zhan-Gang Han1, Xiao-Qing Chang, Jin-Shuang Yan
1College of Chemistry and Material Science, Hebei Normal University , Shijiazhuang 050024, China.
Abstract:
A novel aluminum-containing, bimolybdenum-capped Keggin-type polyoxomolybate cluster of the {AlMo12O40(MoO2)2} anion has been synthesized and characterized. This is the first experimentally determined Keggin-type {AlMo12O40} polyoxoanion. The polyoxometalate crystal exhibits high selectivity toward the heterogeneous catalytic oxidation of cyclohexanol to cyclohexanone.
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