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Updated: May 3, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Effect of ligand substituent on the reactivity of Ni(II) complexes towards oxygen
Abstract:
Two radical-containing Ni(II) complexes having either parent salicylidene (complex 1) or 3,5-di-tert-butylsalicylidene (complex 2) in the ligand backbone were synthesized. Complex 2 underwent ligand centered C–H activation by aerial oxygen, forming the corresponding amide complex (2a). The UV-Vis/NIR spectral changes upon purging of molecular oxygen to 2 in CH2Cl2, alongwith ESI-MS analysis indicated the generation of Ni–oxygen/dioxygen species as the intermediate(s) for the amide formation. Interestingly, nonparticipation of the ligand centered π-radical in the oxidation process was observed.
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