Related Experiment Video
Updated: May 3, 2026
Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of PhosphorusI
Published on: November 22, 2016
Sodium phosphaethynolate as a building block for heterocycles
Xiaodan Chen1, Simone Alidori, Florian Frank Puschmann
1Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zurich (Switzerland).
Abstract:
Phosphorus-containing heterocycles have evolved from laboratory curiosities to functional components, such as ligands in catalytically active metal complexes or molecular constituents in electronic devices. The straightforward synthesis of functionalized heterocycles on a larger scale remains a challenge. Herein, we report the use of the phosphaethynolate (OCP)(-) anion as a building block for various sterically unprotected and functionalized hydroxy substituted phosphorus heterocycles. Because the resulting heterocycles are themselves anions, they are building blocks in their own right and allow further facile functionalization. This property may be of interest in coordination chemistry and material science.
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