Related Experiment Video
Updated: May 3, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Bis(2-meth-oxy-benzyl-ammonium) di-aqua-bis-(di-hydrogen diphosphato-κ(2) O,O')manganate(II) dihydrate
Adel Elboulali1, Samah Akriche1, Mohamed Rzaigui1
1Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.
Abstract:
The asymmetric unit of the title compound, (C8H12NO)2[Mn(H2P2O7)2(H2O)2]·2H2O, consists of half an Mn(II) complex anion, a 2-meth-oxy-benyl-ammonium cation and a solvent water mol-ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa-hedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol-ecules. In the crystal, the components are linked by O-H⋯O and N-H⋯O hydrogen bonds, forming layers parallel to (100). An intra-molecular N-H⋯O hydrogen bond is also observed.
Related Concept Videos
Ionic Compounds: Formulas and Nomenclature
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate
Radical Oxidation of Allylic and Benzylic Alcohols
Molecular Compounds: Formulas and Nomenclature
Common Ion Effect
Qualitative Analysis
For instance, group IV...

