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Updated: May 3, 2026

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chlorido-zincate
Muhammad Akhtar1, Mohammed Fettouhi2, Maqsood Ahmed3
1Department of Chemistry, Quaid-i-Azam University, Islamabad, Pakistan.
Abstract:
The asymmetric unit of the title compound, (C6H18N2)[ZnCl4], consists of one tetra-chlorido-zincate anion and two half-N,N,N'N'-tetra-methyl-ethylenedi-ammonium cations. Each of the two di-ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The Zn(II) atom has a slightly distorted tetra-hedral coordination environment. The cations and anions are connected via N-H⋯Cl hydrogen bonds into chains extending along [0-11].
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