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Updated: May 3, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
1-(2-Bromo-meth-yl-1-phenyl-sulfonyl-1H-indol-3-yl)propan-1-one
M Umadevi1, V Saravanan2, R Yamuna3
1Research Scholar (Chemistry), Bharathiyar University, Coimbatore 641 046, Tamilnadu, India.
Abstract:
In the title compound, C18H16BrNO3S, the dihedral angle between the phenyl ring and the indole ring system is 89.91 (11)°. The mol-ecular structure features weak C-H⋯O and C-H⋯Br hydrogen bonds. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds, forming chains along the a-axis direction. The chains are further linked by C-H⋯π inter-actions, forming a layer parallel to the ab plane.
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