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A novel manganese-doped large polyoxotitanate nanocluster
Yang Chen1, Elzbieta Trzop, Anna Makal
1Chemistry Department, University at Buffalo, SUNY, Buffalo, New York 14260-3000, USA.
Dalton Transactions (Cambridge, England : 2003)
|January 25, 2014
Abstract:
A large manganese-doped polyoxotitanate nanocluster Ti28MnO38(OEt)40H2, has been synthesized solvothermally. Its structure is arranged around the four-coordinate Mn(2+) dopant atom in a Keggin-type structure. A significant reduction of the band gap relative to that of undoped polyoxotitanate clusters is observed.
