Related Experiment Video
Updated: May 3, 2026
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Ferrocene-modified carbon nitride for direct oxidation of benzene to phenol with visible light
Xiangju Ye1, Yanjuan Cui, Xinchen Wang
1State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183920097.
Abstract:
Ferrocene moieties were heterogenized onto carbon nitride polymers by a covalent -C=N- linkage bridging the two conjugation systems, enabling the merging of the redox function of ferrocene with carbon nitride photocatalysis to construct a heterogeneous Photo-Fenton system for green organocatalysis at neutral conditions. The synergistic donor-acceptor interaction between the carbon nitride matrix and ferrocene group, improved exciton splitting, and coupled photocatalytic performance allowed the direct synthesis of phenol from benzene in the presence of H2 O2 under visible light irradiation. This innovative modification method will offer an avenue to construct functionalized two-dimensional polymers useful also for other green synthesis processes using solar irradiation.
More Related Videos
05:34Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
Published on: December 16, 2019
10:10Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
Published on: July 28, 2018
Related Concept Videos
Benzene to Phenol via Cumene: Hock Process
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
Electrophilic Aromatic Substitution: Nitration of Benzene
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism
Reactions at the Benzylic Position: Oxidation and Reduction
Hydrolysis of Chlorobenzene to Phenol: Dow Process