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Updated: May 3, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Double C(arom)-H activation associated with etheral oxygen insertion to phenazine architecture in oxidisable
Suman K Roy1, Subhas Samanta, Nabanita Saha Chowdhury
1Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700 032 (India).
Abstract:
Three examples of unusual double aromatic CH bond activation associated with insertion of etheral oxygen atom to phenazine architecture in Ru(III) complexes are reported. The chemical transformations have led to the formation of new Ru(IV) complexes with angular pentacyclo heterocyclic ligands. A mechanistic investigation indicates that the overall process is a combination of successive steps involving air (O2 ) and H2 O.
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