Photo- and thermo-induced spin crossover in a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule
Abhishake Mondal1, Yanling Li, Lise-Marie Chamoreau
1Sorbonne Universités, UPMC Univ. Paris 06, UMR 8232, IPCM, F-75005, Paris, France. rodrigue.lescouezec@upmc.fr.
Chemical Communications (Cambridge, England)
|February 5, 2014
Abstract:
The self-assembly of [Mo(V)(CN)8](3-) and [Fe(II)(bik)2(S)2](2+) affords a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.
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