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Updated: May 3, 2026

Probe Type II Band Alignment in One-Dimensional Van Der Waals Heterostructures Using First-Principles Calculations
Published on: October 12, 2019
Ag2S-AgInS2: p-n junction heteronanostructures with quasi type-II band alignment
Riya Bose1, Goutam Manna, Santanu Jana
1Centre for Advanced Materials and Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India. camnp@iacs.res.in camrb@iacs.res.in.
Abstract:
We report here the fabrication of a p-n junction diode in a single nanostructure by synthesizing a heterostructure involving n-type AgInS2 and p-type Ag2S. The quasi type-II band alignment between these ternary-binary semiconductors in the p-n junction heterostructures also slows down the carrier recombination rate and the heterostructures show rectification behavior. Hence, they can be used as an active material for fabrication of bulk heterojunction photovoltaic devices without any additional semiconductor material or dye required for charge separation or formation of a p-n junction.
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