Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles
Michael J Geier1, Michel R Gagné
1Caudill Laboratories, Department of Chemistry, University of North Carolina at Chapel Hill , Chapel Hill, North Carolina 27599-3290, United States.
Abstract:
Application of a tridentate NHC containing pincer ligand to Pt catalyzed cascade cyclization reactions has allowed for the catalytic, diastereoselective cycloisomerization of biogenic alkene terminated substrates to the their polycyclic counterparts.
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