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Related Concept Videos

Complexation Equilibria: Factors Influencing Stability of Complexes01:09

Complexation Equilibria: Factors Influencing Stability of Complexes

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Ionic Association01:28

Ionic Association

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The ionic association is the association of oppositely charged ions in an electrolyte solution to form ion pairs. Bjerrum defined ion pairs as two oppositely charged ions whose electrostatic attraction exceeds the thermal energy of the system, typically expressed as 2kT. Electrostatic attraction depends on ionic charge, separation distance, and the dielectric constant of the medium. Thermal energy, represented by kT, reflects the tendency of ions to move independently due to molecular motion.
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Ionic Bonds00:42

Ionic Bonds

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Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
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Lewis Acids and Bases

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This lesson delves into Lewis acids and bases in the context of the octet rule for electron-deficient compounds. Here, the concept is discussed, emphasizing the group 13 elements like boron or aluminium. Since group 13 elements possess three valence electrons, they form trivalent compounds with a sextet of electrons and a vacant orbital for the central atom. Consequently, these electron-deficient compounds accept electrons from other species to complete their octet in a chemical reaction. They...
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Boron clusters as highly stable magnesium-battery electrolytes.

Tyler J Carter1, Rana Mohtadi, Timothy S Arthur

  • 1Department of Chemistry, University of Michigan (USA).

Angewandte Chemie (International Ed. in English)
|February 13, 2014
PubMed
Summary

Boron clusters offer a novel approach for designing stable, noncorrosive magnesium-battery electrolytes. A new carborane-based electrolyte demonstrates excellent performance, paving the way for advanced magnesium battery technology.

Keywords:
carboranesclusterselectrochemistrymagnesiumrechargeable batteries

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Inorganic Chemistry

Background:

  • Magnesium batteries are promising energy storage devices but require advanced electrolytes.
  • Current electrolytes often face challenges with stability, compatibility, and corrosion.

Purpose of the Study:

  • To introduce boron clusters as a novel concept for designing magnesium-battery electrolytes.
  • To develop and evaluate a new carborane-based electrolyte for magnesium batteries.

Main Methods:

  • Synthesis of a novel carborane-based compound.
  • Incorporation of a magnesium-centered complex anion into the electrolyte.
  • Electrochemical performance testing of the new electrolyte in a magnesium battery system.

Main Results:

  • The novel carborane-based electrolyte exhibits high stability and magnesium-battery compatibility.
  • The electrolyte demonstrates excellent performance, suggesting its suitability for magnesium batteries.
  • The proposed boron cluster concept proves effective for electrolyte design.

Conclusions:

  • Boron clusters represent a promising new direction for designing high-performance magnesium-battery electrolytes.
  • The developed carborane-based electrolyte offers a viable solution to current electrolyte limitations.
  • This research opens new avenues for achieving challenging design targets in magnesium battery technology.