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Synthesis of pyridine N-oxide-BF₂CF₃ complexes and their fluorescence properties
Tomoaki Nishida1, Aiko Fukazawa, Eriko Yamaguchi
1Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).
Abstract:
Pyridine N-oxide-BF2CF3 and -BF2C2F5 complexes and their derivatives were synthesized. Most of the complexes show fluorescence both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. A fluorophore with a high solvent dependency could also be produced. Since such compounds can be synthesized on a gram scale in high yield, and are stable to oxygen, water, and heat, the complexes hold great potential as organic functional materials.
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