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Updated: May 3, 2026

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Tuning porosity and activity of microporous polymer network organocatalysts by co-polymerisation
Johannes Schmidt1, Dipti Sankar Kundu, Siegfried Blechert
1Technische Universität Berlin, Hardenbergstraße 40, 10623 Berlin, Germany. johannes.schmidt@tu-berlin.de.
Abstract:
Microporous polymer networks based on binaphthyl phosphoric acids are suitable heterogeneous asymmetric organocatalysts. Herein we show that the porous characteristics of such networks can be fine-tuned by co-polymerisation. This enables us to investigate the influence of the surface area and porosity in microporous networks on their catalytic performance. In this case, the activity of the polymers in an asymmetric hydrogenation reaction is increased by the use of polymers with higher surface areas.
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