Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis
Juan Olguín1, Helge Müller-Bunz, Martin Albrecht
1School of Chemistry & Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland. martin.albrecht@ucd.ie.
Abstract:
Porphyrin rhodium(III) complexes accommodate one or two NHC ligands in the apical position, which leads to severe porphyrin distortion and dearomatization. The strain in the bis(carbene) complex induces facile carbene dissociation and the formation of a catalytically active site for alcohol oxidation.
More Related Videos
10:51The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
10:52Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
Related Concept Videos
Carbocations
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation
Aldehydes and Ketones with HCN: Cyanohydrin Formation Mechanism
Catalysis
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3
Aldehydes and Ketones with HCN: Cyanohydrin Formation Overview
