Related Experiment Video
Updated: May 2, 2026
Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Evidence of antiferromagnetic and ferromagnetic superexchange interactions in bulk TbMn(1-x)Cr(x)O(3)
Abstract:
Powder samples of solid solution TbMn1-xCrxO3 (0 ≤ x ≤ 1) were synthesized via a facile solution route. The substitution of non-Jahn–Teller active Cr3+ for Mn3+ in TbMnO3 was found to decrease the unit cell volume and orthorhombic distortion. TbMn1-xCrxO3 with low Cr content (x ≤ 0.33) exhibited magnetic behavior similar to the pure TbMnO3 sample. However, ferromagnetic-like Mn–Cr interactions were introduced in these samples and maximum magnetic field coercivity and remanence were found at x ~0.33. For x ≥ 0.5, signatures of a canted G-type antiferromagnetic ordering similar to pure TbCrO3 were observed. The Mn3+/Cr3+ spins rotate from parallel to the a-axis to parallel to the c-axis with increasing Cr content. Based on the magnetization results, a magnetic phase diagram for bulk solid solution TbMn1-xCrxO3 has been proposed for the first time.
More Related Videos
09:06Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
Published on: March 24, 2019
06:49Radio Frequency Magnetron Sputtering of GdBa2Cu3O7âˆ'ÃŽ ´/ La0.67Sr0.33MnO3 Quasi-bilayer Films on SrTiO3 STO Single-crystal Substrates
Published on: April 12, 2019
Related Concept Videos
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than...
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
01:31Ferromagnetism
02:42Valence Bond Theory
02:18X-ray Crystallography
Diffraction
Diffraction is the change in the direction of travel experienced by an electromagnetic wave when it encounters a physical barrier whose dimensions are comparable to those of the wavelength of the light. X-rays are electromagnetic radiation with wavelengths about as long as the distance between neighboring...