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Updated: May 2, 2026
Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
A three-dimensional Zn(II) coordination framework:
Cai Xia Yu1, Feng Zhao1, Min Zhou1
1College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000, Henan, People's Republic of China.
Abstract:
In the title coordination polymer, [Zn2(C14H8N2O4)2(C12H10N2)]n, the asymmetric unit contains one Zn(II) cation, two halves of 2,2'-(diazene-1,2-diyl)dibenzoate anions (denoted L(2-)) and half of a 1,2-bis(pyridin-4-yl)ethene ligand (denoted bpe). The three ligands lie across crystallographic inversion centres. Each Zn(II) centre is four-coordinated by three O atoms of bridging carboxylate groups from three L(2-) ligands and by one N atom from a bpe ligand, forming a tetrahedral coordination geometry. Two Zn(II) atoms are bridged by two carboxylate groups of L(2-) ligands, generating a [Zn2(CO2)2] ring. Each loop serves as a fourfold node, which links its four equivalent nodes via the sharing of four L(2-) ligands to form a two-dimensional [Zn2L4]n net. These nets are separated by bpe ligands acting as spacers, producing a three-dimensional framework with a 4(6)6(4) topology. Powder X-ray diffraction and solid-state photoluminescence were also measured.
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