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Published on: September 29, 2023
"Click"-extended nitrogen-rich metal-organic frameworks and their high performance in CO2-selective capture
Pei-Zhou Li1, Xiao-Jun Wang, Kang Zhang
1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore. zhaoyanli@ntu.edu.sg.
Abstract:
Metal-organic frameworks (MOFs), NTU-111, 112, 113 were assembled from diversely "click"-extended tetracarboxylates. Since the MOFs were incorporated with exposed metal sites and accessible nitrogen-rich triazole units, they exhibited high CO2-selective capture capabilities supported by experimental investigations and molecular simulation studies.

