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Updated: May 2, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
Record high electron mobility of 6.3 cm² V⁻¹ s⁻¹ achieved for polymer semiconductors using a new building block
Bin Sun1, Wei Hong, Zhuangqing Yan
1Department of Chemical Engineering, Waterloo Institute for Nanotechnology (WIN), Waterloo, ON, N2L 3G1, Canada.
Abstract:
A new electron acceptor building block, 3,6-di(pyridin-2-yl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H)-dione (DBPy), is used to construct a donor-acceptor polymer, PDBPyBT. This polymer exhibits a strong self-assembly capability, to form highly crystalline and oriented thin films with a short π-π stacking distance of 0.36 nm. PDBPyBT shows ambipolar charge-transport performance in organic thin-film transistors, reaching a record high electron-mobility value of 6.30 cm(2) V(-1) s(-1).
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