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A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
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Palladium-catalyzed C-S activation/aryne insertion/coupling sequence: synthesis of functionalized 2-quinolinones

Ying Dong, Bangyu Liu, Peng Chen

    Angewandte Chemie (International Ed. in English)
    |March 29, 2014
    PubMed
    Summary

    This study introduces a new palladium-catalyzed reaction using arynes and ketene dithioacetals to synthesize functionalized 2-quinolinones. This method offers a selective and efficient route to valuable heterocyclic compounds.

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