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Related Concept Videos

Surface Active Agents01:27

Surface Active Agents

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Surfactants, named for their behavior at interfaces, positively adsorb at the interfaces of two phases, reducing interfacial tension. Their versatility as emulsifiers, detergents, and foaming agents stems from this ability. Surfactants, often termed amphiphiles, share the property of amphipathy, with molecules having both hydrophilic and hydrophobic portions. The hydrophilic part is called the head, and the hydrophobic part, including an elongated alkyl substituent, forms the tail.Surfactants...
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Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...
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The process of breathing, inhaling and exhaling, involves the coordinated movement of the chest wall, the lungs, and the muscles that move them. Two muscle groups with important roles in breathing are the diaphragm, located directly below the lungs, and the intercostal muscles, which lie between the ribs. When the diaphragm contracts, it moves downward, increasing the volume of the thoracic cavity and creating more room for the lungs to expand. When the intercostal muscles contract, the ribs...
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Surfactant-free switchable emulsions using CO2-responsive particles.

Chen Liang1, Qingxia Liu, Zhenghe Xu

  • 17th Floor, ECERF, Department of Chemical and Material Engineering, University of Alberta , Edmonton, Alberta T6G 2V4, Canada.

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Summary
This summary is machine-generated.

Bi-wetting particles stabilize emulsions by controlling interfacial area. Introducing CO2 alters particle wettability, destabilizing emulsions, while its removal re-establishes stability.

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Area of Science:

  • Colloid and Surface Science
  • Materials Science
  • Chemical Engineering

Background:

  • Surfactant-free emulsions offer environmental benefits but require effective stabilization.
  • Bi-wetting particles can stabilize emulsions by adsorbing at the oil-water interface.
  • Particle wettability dictates emulsion type (oil-in-water or water-in-oil).

Purpose of the Study:

  • To investigate the use of CO2-responsive silica particles for tunable emulsion stabilization.
  • To explore the impact of CO2-induced wettability changes on emulsion stability.
  • To demonstrate reversible emulsion destabilization and re-stabilization.

Main Methods:

  • Grafting CO2-responsive and hydrophobic functional groups onto silica particles.
  • Preparing oil-in-water and water-in-oil emulsions using functionalized bi-wetting particles.
  • Introducing and removing CO2 gas to alter particle wettability and observe emulsion behavior.

Main Results:

  • Particles with CO2-responsive groups alone stabilized oil-in-water emulsions.
  • Particles with both CO2-responsive and hydrophobic groups stabilized water-in-oil emulsions.
  • CO2 introduction destabilized emulsions by increasing particle wettability and surface charge, leading to phase separation.
  • CO2 removal via air sparging re-established emulsion stability.

Conclusions:

  • CO2-responsive bi-wetting particles provide a mechanism for tunable emulsion stabilization.
  • The CO2-induced change in particle wettability is a key factor in controlling emulsion stability.
  • This system offers a pathway for stimuli-responsive emulsion design and control.