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Published on: October 15, 2015
Extraction of copper from an oxidized (lateritic) ore using bacterially catalysed reductive dissolution.
Ivan Nancucheo1, Barry M Grail, Felipe Hilario
1College of Natural Sciences, Bangor University, Deiniol Road, Bangor, LL57 2UW, UK.
Reductive bioleaching using Acidithiobacillus ferrooxidans efficiently extracts copper from oxidized lateritic ores. This microbial process significantly enhances copper recovery compared to conventional methods.
Area of Science:
- * Geomicrobiology
- * Hydrometallurgy
- * Bioprocessing
Background:
- * Lateritic ores contain valuable base metals like copper.
- * Conventional extraction methods face challenges with complex ore mineralogy.
- * Microbial processes offer alternative, potentially more efficient, metal recovery strategies.
Purpose of the Study:
- * To investigate the efficacy of reductive bioleaching for copper extraction from oxidized lateritic ore.
- * To evaluate the role of Acidithiobacillus ferrooxidans in copper solubilization.
- * To compare reductive bioleaching performance against aerobic and sterile conditions.
Main Methods:
- * Bioleaching experiments conducted in controlled stirred reactors using Acidithiobacillus ferrooxidans.
- * Ore treated under acidic, reducing conditions with sulfur as electron donor and ferric iron as electron acceptor.
- * Comparison of copper extraction yields in anaerobic microbial, aerobic microbial, and sterile anoxic reactors.
Main Results:
- * Significantly higher copper leaching achieved through bacterially catalyzed reductive dissolution (up to 78% extraction).
- * Effective extraction of copper from both acid-labile and ferric iron-associated minerals.
- * Soluble copper (I) and iron (II) were observed in anaerobic conditions, oxidizing to copper (II) and iron (III) upon aeration.
- * Bacterial inoculum size critically influenced leaching rate and yield.
Conclusions:
- * Reductive bioleaching is a highly effective method for extracting copper from oxidized lateritic ores.
- * Acidithiobacillus ferrooxidans plays a crucial role in enhancing copper recovery via reductive dissolution.
- * This study supports the potential of reductive bioprocessing to expand the scope of biomining for oxidized metal deposits.
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