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Solvent-free synthesis of new metal phosphite-oxalates with open-framework structures
Lin Liu1, Daibing Luo, Defu Li
1College of Chemistry, Sichuan University, Chengdu 610064, P. R. China. zhienlin@scu.edu.cn.
Dalton Transactions (Cambridge, England : 2003)
|April 11, 2014
Abstract:
Two new metal phosphite-oxalates, CN3H6·Co(H2PO3)(C2O4) (1) and (CN3H6)2·Mn2.5(HPO3)(C2O4)2.5(H2O)·H2O (2), have been prepared under solvent-free conditions. The two open-framework compounds have diamondoid and pillared-layered structures, respectively. Their photoluminescence and magnetic properties were also investigated.
