Desalination feasibility study of an industrial NaCl stream by bipolar membrane electrodialysis

The industrial implementation of alternative technologies in the processing of saline effluent streams is a topic of growing importance. In this technical feasibility study, the desalination of an industrial saline stream containing about 75 g L(-1) NaCl contaminated with some organic matter using bipolar membrane electrodialysis (EDBM) was investigated on lab-scale. Bipolar membranes of two different manufacturers (PCA - PolymerChemie Altmeier GmbH and FuMA-Tech GmbH) were tested and compared in terms of electrical resistance, current efficiency and purity of the produced acid and base stream. In both cases, almost complete desalination (>99%) was achieved and simultaneously HCl and NaOH were produced with a concentration between 1.5 and 2 M with a relatively good purity. The Fumasep bipolar membranes scored slightly better for electrical resistance and current efficiency. On the other hand, slightly higher current densities were achieved with PCA bipolar membranes. Simultaneously, some information was obtained on the transport behavior of the organic matter present in the saline stream. It was observed that a transport competition occurred between the organic matter and the accompanying chlorides. From this lab-scale study it was concluded that EDBM is a promising and attractive technology in the area of saline effluent reclamation and reuse.