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Bacterial cellulose/silica nanocomposites: preparation and characterization
Alireza Ashori1, Somayeh Sheykhnazari2, Taghi Tabarsa2
1Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), P.O. Box 15815-3538, Tehran, Iran.
Carbohydrate Polymers
|April 23, 2014
Summary
Researchers developed bacterial cellulose (BC)/silica nanocomposites for enhanced material properties. Optimal conditions yielded significant improvements in tensile strength and Young
Area of Science:
- Materials Science
- Biomaterials Engineering
- Nanotechnology
Background:
- Bacterial cellulose (BC) is a promising biomaterial, but its mechanical properties require enhancement for broader applications.
- Developing novel nanocomposites can improve BC's performance.
- Silica incorporation is a viable strategy to create advanced BC-based materials.
Purpose of the Study:
- To prepare and characterize novel bacterial cellulose (BC)/silica nanocomposites.
- To investigate the effects of tetraethoxysilane (TEOS) concentration and pressing parameters on material properties.
- To determine the optimal conditions for producing BC/silica nanocomposites with superior mechanical performance.
Main Methods:
- BC hydro-gel was immersed in tetraethoxysilane (TEOS) solutions.
- Treated BC matrices were pressed at 120 °C and 2 MPa to form translucent sheets.
- Variable factors included TEOS concentration (3-7%) and press time (8-12 min).
- Characterization involved FE-SEM, FTIR, SEM, tensile strength, and Young's modulus measurements.
Main Results:
- All BC/silica composites exhibited good fiber dispersion and matrix adhesion.
- FE-SEM confirmed nano-scale silica embedded within the BC matrix.
- Optimal conditions (7% TEOS, 8 min press time) resulted in a 35-fold increase in tensile strength (113 MPa) and an 18-fold increase in Young's modulus (1.46 GPa).
- Increased press time negatively impacted mechanical properties.
Conclusions:
- The preparation method successfully yielded BC/silica nanocomposites with enhanced mechanical properties.
- Strong chemical interactions between cellulose and silica phases were confirmed by FTIR.
- The study identified optimal processing parameters for maximizing the performance of BC/silica nanocomposites.

