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Updated: Apr 30, 2026
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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
4-Hy-droxy-3-meth-oxy-benzaldehyde 4-phenyl-thio-semicarbazone
Adriano Bof de Oliveira1, Bárbara Regina Santos Feitosa1, Christian Näther2
1Departamento de Química, Universidade Federal de Sergipe, Av. Marechal Rondon s/n, Campus, 49100-000 São Cristóvão, SE, Brazil.
Abstract:
In the title compound, C15H15N3O2S, the central C-N-N-C unit has an anti conformation [torsion angle = -170.17 (15)°]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2 (1)°], whereas the substituted ring is rotated out of this plane by only 18.86 (17)°. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds into inversion dimers that are further connected via N-H⋯O and O-H⋯S hydrogen bonds into a three-dimensional network.
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