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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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Synthesis of copolymerized porous organic frameworks with high gas storage capabilities at both high and low
Cuiying Pei1, Teng Ben, Yanqiang Li
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, China. sqiu@jlu.edu.cn.
Chemical Communications (Cambridge, England)
|April 30, 2014
Abstract:
A series of copolymerized porous organic frameworks (C-POFs) were synthesized with monomers of tetrakis(4-bromophenyl)methane and tris(4-bromophenyl)amine in different ratios by a Yamamoto-type Ullmann cross-coupling reaction. These C-POFs exhibit high physicochemical stability, large surface areas and excellent H2, CH4 and CO2 adsorption properties both at low and high pressures.
