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Synthesis, characterization, and metal ion coordination of a multichromophoric highly luminescent polysulfurated
Andrea Fermi1, Paola Ceroni, Myriam Roy
1Department of Chemistry "G. Ciamician", University of Bologna, Via Selmi 2, 40126, Bologna (Italy), Fax: (+39) 051-2099456; Aix-Marseille Université, CNRS, CINaM UMR 7325, 163 Ave. de Luminy, 13288 Marseille (France), Fax: (+33) 491829155.
Abstract:
We have designed a new multichromophoric system based on a tetra(phenylthio)pyrene core appended with four terpyridine units. The system behaves as a molecular antenna that collects light with the peripheral units and funnels the energy to the very highly luminescent core. The addition of metals ions to the investigated system can not only switch the direction of the intramolecular energy transfer, but also control the formation of three-dimensional nanoscopic objects in a dual function.
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