γ-Fe2O3-MWNT/poly(p-phenylenebenzobisoxazole) composites with excellent microwave absorption performance and thermal stability
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Updated: Apr 30, 2026

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
Yi Chen1, Xiaoyun Liu, Xiaoyang Mao
1Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China. liuxiaoyun@ecust.edu.cn qxzhuang@ecust.edu.cn.
Abstract:
Ferromagnetic γ-Fe2O3 nanoparticles were successfully loaded into multi-walled carbon nanotubes (MWNTs) as probed by transmission electron microscopy. Upon incorporation of the γ-Fe2O3-MWNTs into poly(p-phenylenebenzobisoxazole) (PBO), a conjugated polymer with high mechanical strength and outstanding thermal and oxidative stability, microwave absorbing materials were obtained. Attributed to the special structure of the γ-Fe2O3-MWNTs, synergistic effects on dielectric loss and magnetic loss, and a better matched characteristic impedance of the composites were achieved. The optimal minimum reflection loss reached -32.7 dB at 12.09 GHz on a composite containing 12 wt% γ-Fe2O3-MWNTs with a thickness of 2.7 mm, and the corresponding bandwidth below -5 dB was 6.2 GHz. This demonstrated its potential applications as a low-density microwave absorbing material operating under extreme environments.

