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Solar hydrogen from an aqueous, noble-metal-free hybrid system in a continuous-flow sampling reaction system

Xiaobo Li1, Antony J Ward, Anthony F Masters

  • 1Laboratory of Advanced Catalysis for Sustainability, School of Chemistry, University of Sydney, NSW, 2006 (Australia), Fax: (+61) 2-9351-3329.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|May 16, 2014
PubMed

Keywords:
continuous flowgraphenehydrogenkineticsphotochemistry

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Fast Reactions01:27

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Fast reactions occurring in times shorter than the time needed to mix reactants pose a unique challenge for investigation. In a liquid-phase continuous-flow system, reactants A and B are swiftly pushed into the mixing chamber, where mixing occurs within 1 ms. The reaction mixture then flows through an observation tube, and one measures light absorption to determine species concentrations at various points of the tube. This method is most appropriate when relatively large volumes of reactants...