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The Phase Rule01:20

The Phase Rule

140
The phase rule describes the relationship between the variance (degrees of freedom), the number of components, and the number of phases in a system at equilibrium.Variance is a concept that denotes the number of independent intensive properties (properties are those that do not depend on the amount of material in the system), such as temperature, pressure, and composition, that can be altered without impacting the number of phases in equilibrium.In a single-component system, such as pure water,...
140
Three-Phase Voltages01:30

Three-Phase Voltages

815
A three-phase generator produces three voltages that are equal in magnitude but have a phase difference of 120 degrees. This identical magnitude and equal phase separated voltages are known as the balanced voltages and help to minimize power loss while ensuring a steady delivery of energy to connected loads. As voltage sources in a three-phase system can be configured in a wye or a delta formation, the loads connected to these systems can also be arranged in either configuration. This...
815
Transfer function and Bode Plots-II01:23

Transfer function and Bode Plots-II

1.0K
In the standard form, the transfer function is shown in constant gain, poles/zeros at origin, simple poles/zeros, and quadratic poles/zeros; each contributing uniquely to the system's overall response. The term represents the magnitude of the simple zero:
1.0K
Phase Diagrams of Ternary Systems01:28

Phase Diagrams of Ternary Systems

155
Consider a ternary system, which is composed of three components: water (W), ethanoic acid (E), and trichloromethane (T). Here, Ethanoic acid (E) is fully miscible with both water (W) and trichloromethane (T), meaning it can mix entirely with either of them. However, water and trichloromethane have partial miscibility, meaning they can only mix to a certain extent, beyond which two separate phases will form.The phase diagram of a ternary system is represented as an equilateral triangle, where...
155
¹H NMR: Pople Notation01:09

¹H NMR: Pople Notation

2.4K
The Pople nomenclature system classifies spin systems based on the difference between their chemical shifts. Coupled spins are denoted by capital letters with subscripts indicating the number of equivalent nuclei. When the coupled nuclei have well-separated chemical shifts, they are assigned letters that are far apart in the alphabet, such as A and X. When the difference in chemical shifts is small, coupled nuclei are named using adjacent letters of the alphabet (AB, MN, or XY).
A proton...
2.4K
Power in a Three-Phase Circuit01:15

Power in a Three-Phase Circuit

750
Three-phase systems have two configurations: the wye and delta. A star configuration can be three or four wires; in a delta configuration, the components are connected in a closed loop. Instantaneous power refers to the power value at a precise moment, and in a balanced three-phase system, it is constant. This is because the sum of the instantaneous powers in the three phases remains steady over time, despite individual fluctuations, due to the symmetry and phase relationship. The total...
750

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Related Experiment Video

Updated: Apr 29, 2026

Shaping the Amplitude and Phase of Laser Beams by Using a Phase-only Spatial Light Modulator
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Shaping the Amplitude and Phase of Laser Beams by Using a Phase-only Spatial Light Modulator

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mP-BaP₃: a new phase from an old binary system.

Juli-Anna Dolyniuk1, Derrick C Kaseman, Sabyasachi Sen

  • 1Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, CA 95616 (USA).

Chemistry (Weinheim an Der Bergstrasse, Germany)
|May 23, 2014
PubMed
Summary

A new barium triphosphide polymorph, mP-BaP3, featuring a unique 2D phosphorus layer, has been discovered. This material exhibits distinct thermal stability and properties compared to its 1D chain polymorph, mS-BaP3.

Keywords:
crystal structureelectronic structurepolyphosphidesolid-state NMR spectroscopyzintl phases

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Area of Science:

  • Materials Science
  • Solid-State Chemistry
  • Crystallography

Background:

  • Barium triphosphide (BaP3) exists in different structural forms (polymorphs).
  • Previous research identified a polymorph with one-dimensional phosphorus chains (mS-BaP3).
  • Understanding structural variations is key to predicting material properties.

Purpose of the Study:

  • To discover and characterize a new polymorph of barium triphosphide.
  • To investigate the structural differences between the new polymorph and the previously known one.
  • To explore the impact of structural variations on material properties.

Main Methods:

  • Single-crystal X-ray diffraction for structural determination.
  • Differential Scanning Calorimetry (DSC) for thermal analysis.
  • Solid-state Nuclear Magnetic Resonance (NMR) spectroscopy ((31)P MAS NMR).
  • UV/Vis and surface photovoltage (SPV) spectroscopies.
  • Quantum-chemical calculations.

Main Results:

  • Discovery and characterization of a new barium triphosphide polymorph, mP-BaP3, crystallizing in the monoclinic space group P2₁/c.
  • mP-BaP3 exhibits a unique two-dimensional phosphorus layer structure, contrasting with the one-dimensional chains in mS-BaP3.
  • The new phase has a 1.4% larger unit-cell volume than mS-BaP3.
  • Significant differences in thermal stability and electronic/optical properties were observed between the two polymorphs.

Conclusions:

  • The discovery of mP-BaP3 expands the known structural diversity of barium triphosphides.
  • Structural differences, specifically the dimensionality of phosphorus anions, significantly influence the material's properties.
  • This study highlights the importance of polymorphs in tuning the characteristics of inorganic compounds.