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Stretchable liquid-crystal blue-phase gels.

F Castles1, S M Morris2, J M C Hung3

  • 11] Centre of Molecular Materials for Photonics and Electronics, Department of Engineering, University of Cambridge, 9 JJ Thomson Avenue Cambridge CB3 0FA, UK [2] Department of Materials, University of Oxford, Parks Road Oxford OX1 3PH, UK.

Nature Materials
|June 2, 2014
PubMed
Summary
This summary is machine-generated.

Researchers fabricated a stretchable blue phase I gel, a 3D photonic crystal with tunable optical properties. Mechanically deformed blue phases show a Pockels electro-optic effect, enabling new low-voltage devices.

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Area of Science:

  • Materials Science
  • Polymer Science
  • Optoelectronics

Background:

  • Liquid-crystalline polymers combine optical and mechanical properties.
  • Stretchable liquid-crystalline polymers exist in nematic, chiral-nematic, and smectic mesophases.
  • These materials exhibit unique behaviors not seen in independent components.

Purpose of the Study:

  • To fabricate a stretchable gel of blue phase I liquid crystal.
  • To investigate the electro-optic and strain-optic properties of this material.
  • To explore its potential for low-voltage electro-optic devices.

Main Methods:

  • Fabrication of a stretchable blue phase I gel.
  • Characterization of its self-assembled 3D photonic crystal structure.
  • Analysis of electro-optic switching under applied voltage and strain manipulation.

Main Results:

  • Successful fabrication of a stretchable blue phase I gel.
  • Demonstration of electro-optic switchability under moderate voltage.
  • Observation of optical property manipulation via applied strain.
  • Discovery of a Pockels electro-optic effect in mechanically deformed blue phase I.

Conclusions:

  • Stretchable blue phase I gels are viable 3D photonic crystals.
  • These materials offer tunable optical properties via strain and voltage.
  • The observed Pockels effect presents new opportunities for low-voltage electro-optic applications.