Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

9-Allyl-9H-fluoren-9-ol.

Kyle S Knight1, Harvey B Wood1

  • 1Department of Chemistry, The University of Tennessee at Chattanooga, Chattanooga, TN 37403, USA.

Acta Crystallographica. Section E, Structure Reports Online
|June 19, 2014
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Crystal structure of (E)-4,4'-(but-2-ene-1,4-di-yl)bis-(2-meth-oxy-phenol).

Acta crystallographica. Section E, Crystallographic communications·2015
Same author

Crystal structure of N-[4-amino-5-cyano-6-(methyl-sulfan-yl)pyridin-2-yl]-2-chloro-acetamide.

Acta crystallographica. Section E, Crystallographic communications·2015
Same author

Crystal structure of N-[4-amino-5-cyano-6-(methyl-sulfan-yl)pyridin-2-yl]acetamide hemihydrate.

Acta crystallographica. Section E, Crystallographic communications·2015
Same author

Crystal structure of 4,6-di-amino-2-(methyl-sulfan-yl)pyridine-3-carbo-nitrile.

Acta crystallographica. Section E, Crystallographic communications·2015
Same author

Santal monohydrate, an isoflavone isolated from Wye-thia mollis.

Acta crystallographica. Section E, Structure reports online·2014
Same author

Tenulin 0.25-hydrate, a sesquiterpene lactone isolated from Helenium amarum.

Acta crystallographica. Section E, Structure reports online·2013
Same journal

Crystal structure of 1-(piperidin-1-yl)butane-1,3-dione.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of methyl 1-methyl-3,5-diphenyl-7-tosyl-3,6,7,11b-tetra-hydro-pyrazolo-[4',3':5,6]pyrano[3,4-c]quinoline-5a(5H)-carboxyl-ate.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of 4-amino-1-(4-methyl-benz-yl)pyridinium bromide.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of (Z)-3-benz-yloxy-6-[(2-hy-droxy-anilino)methyl-idene]cyclo-hexa-2,4-dien-1-one.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of bis-(1-benzyl-1H-1,2,4-triazole) perchloric acid monosolvate.

Acta crystallographica. Section E, Structure reports online·2015
Same journal

Crystal structure of 2-(di-phenyl-phos-phanyl)phenyl 4-(hy-droxy-meth-yl)benzoate.

Acta crystallographica. Section E, Structure reports online·2015
See all related articles

This study reveals distinct allyl group orientations in two independent C16H14O molecules. Crystal analysis shows these molecules form centrosymmetric tetramers via hydrogen bonds.

Area of Science:

  • Crystallography
  • Organic Chemistry
  • Supramolecular Chemistry

Background:

  • The title compound, C16H14O, was investigated for its structural properties.
  • Understanding molecular arrangements and intermolecular interactions is crucial in crystal engineering.

Purpose of the Study:

  • To elucidate the crystal structure of C16H14O.
  • To analyze the molecular conformation and hydrogen bonding network.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the crystal structure.
  • Analysis of torsion angles and hydrogen bond geometry was performed.

Main Results:

  • The asymmetric unit contains two independent C16H14O molecules with differing allyl group orientations.

Related Experiment Videos

  • The O-C-C(H2)-C(H) torsion angles were found to be -61.01°(13) and -177.43°(10).
  • A centrosymmetric tetramer was formed through O-H⋯O hydrogen bonds, with each hydroxyl group acting as both donor and acceptor.

    • Conclusions:

    • The crystal structure of C16H14O exhibits conformational isomerism in the allyl groups.
    • Intermolecular hydrogen bonding plays a significant role in organizing the crystal lattice, forming supramolecular tetrameric assemblies.