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Updated: Apr 27, 2026

Electrochemically and Bioelectrochemically Induced Ammonium Recovery
Published on: January 22, 2015
A new method for nutrients removal and recovery from wastewater using a bioelectrochemical system
Fei Zhang1, Jian Li1, Zhen He1
1Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA.
Abstract:
Nutrients management is a key task of wastewater treatment and removal of nutrients is usually associated with significant energy/economic cost. A new bioelectrochemical system, named "R(2)-BES", was developed for removing and possibly recovering nutrients from wastewater. This R(2)-BES takes advantage of bioelectricity generation from oxidation of organic compounds to drive ammonium migration out of wastewater, and uses hydroxide ions produced from the cathode reaction as a medium to exchange phosphate ions from wastewater at the same time. Under an applied voltage of 0.8 V, the R(2)-BES removed 83.4 ± 1.3% of ammonium nitrogen and 52.4 ± 9.8% of phosphate, significantly higher than those (3.6 ± 3.7% and 21.1 ± 2.6%) under an open circuit condition. Applying an external voltage can increase current generation, COD removal, and nutrient removal. Those results demonstrate a proof of concept that the R(2)-BES may be potentially applied to remove and recover nutrients through appropriate integration into the existing treatment facilities.
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